ea2526dc73
4 НОВЫЕ СИМЫ (школьная программа 8-11 классов): Органика (organic.js, 1545 строк): - Конструктор молекул: drag атомов C/H/O/N/Cl/S, валентности, click-pair bonds - Авто-определение класса: алкан/алкен/алкин/спирт/альдегид/кислота/эфир/амин/аромат - IUPAC-имена для C1-C10 - Гомологические ряды: 7 рядов с slider количества углеродов, M, T_кип, T_пл - 6 качественных реакций: Br₂ вода, KMnO₄, Ag₂O/NH₃ (серебряное зеркало), Cu(OH)₂, FeCl₃, I₂ Периодическая таблица (periodic.js, 118 элементов): - Стандартный вид 18×9 + лантаноиды/актиноиды - Карточка элемента: Z, M, конфигурация, степени окисления, ЭО, ρ, T_пл/T_кип - Боровская модель электронных оболочек (анимированная) - Подсветка: 11 типов / s/p/d/f-блоки / без подсветки - Графики свойств по периоду/группе (ЭО, M, плотность, T_пл/T_кип) - Поиск по символу/имени/Z/массе Качественный анализ (qualanalysis.js, 24 иона): - 15 катионов: Na/K/NH₄/Mg/Ca/Ba/Al/Fe²⁺/Fe³⁺/Cu/Ag/Pb/Zn/H/OH - 10 анионов: Cl/Br/I/SO₄/SO₃/CO₃/NO₃/PO₄/S²/CH₃COO - 9 реактивов + пламя - 2 режима: «определи ион» и «неизвестное вещество» с логом наблюдений - Анимация капли, осадка с цветом, газовых пузырей, пламени Растворы (solutions.js, 4 режима): - Калькулятор: m_в, m_р-ра, ρ, T → ω, ν, C_М, C_Н с понятной логикой пересчёта - Разбавление с before/after визуализацией - Смешивание двух растворов с правилом рычага - Кривые растворимости 8 веществ + задача перекристаллизации - 15 пресетов веществ (NaCl, NaOH, H₂SO₄, CuSO₄·5H₂O, глюкоза, сахароза, ...) ВИЗУАЛЬНАЯ ПРОКАЧКА (_chem_visuals.js, helper file): 12 функций школьной лабораторной графики: - drawErlenmeyer / drawBeaker / drawBurette / drawTube — proper SVG-paths со шкалой - drawSpiritLamp — стеклянный резервуар + фитиль + анимированное пламя - animateGasBubbles / animatePrecipitateFall — анимация продуктов - drawProductLabel — fade-in/out стрелка ↑/↓ с подписью - drawEduTooltip — bubble с пояснением реакции - drawDeskBackground / drawVesselShadow — лабораторный фон - drawPHStrip — pH-индикаторная полоса с маркером Прокачено 6 chem-сим: chemsandbox, flask, titration, electrolysis, ionexchange, redox Каждая получила: фон парты, тени под колбами, анимированные стрелки продуктов, educational tooltips из поля 'why' реакции. Спиртовка с пламенем в flask. pH-полоса в titration. Каталог теперь: 39 симуляций (было 35 + 4 новых). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
568 lines
22 KiB
JavaScript
568 lines
22 KiB
JavaScript
'use strict';
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/* ====================================================================
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IonExSim — Реакции ионного обмена
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==================================================================== */
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class IonExSim {
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/* ── Данные реакций ──────────────────────────────────────────────── */
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static RXN = {
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ba_so4: {
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name: 'BaCl₂ + Na₂SO₄',
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left: [{ f: 'Ba²⁺', color: '#4FC3F7', count: 7 }, { f: 'Cl⁻', color: '#AED581', count: 14 }],
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right: [{ f: 'Na⁺', color: '#FFD54F', count: 14 }, { f: 'SO₄²⁻', color: '#F48FB1', count: 7 }],
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reacts: ['Ba²⁺', 'SO₄²⁻'],
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spectators: ['Cl⁻', 'Na⁺'],
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product: { f: 'BaSO₄', color: '#E0E0E0' },
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mol: 'BaCl₂ + Na₂SO₄ → BaSO₄↓ + 2NaCl',
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full_ion: 'Ba²⁺ + 2Cl⁻ + 2Na⁺ + SO₄²⁻ → BaSO₄↓ + 2Na⁺ + 2Cl⁻',
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net_ion: 'Ba²⁺ + SO₄²⁻ → BaSO₄↓',
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type: 'precip', pcolor: '#E0E0E0', pname: 'BaSO₄ — белый осадок',
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sign: '↓', signColor: '#E0E0E0',
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},
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ag_cl: {
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name: 'AgNO₃ + NaCl',
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left: [{ f: 'Ag⁺', color: '#E0E0E0', count: 10 }, { f: 'NO₃⁻', color: '#FFCC02', count: 10 }],
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right: [{ f: 'Na⁺', color: '#FFD54F', count: 10 }, { f: 'Cl⁻', color: '#AED581', count: 10 }],
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reacts: ['Ag⁺', 'Cl⁻'],
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spectators: ['NO₃⁻', 'Na⁺'],
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product: { f: 'AgCl', color: '#F5F5F5' },
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mol: 'AgNO₃ + NaCl → AgCl↓ + NaNO₃',
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full_ion: 'Ag⁺ + NO₃⁻ + Na⁺ + Cl⁻ → AgCl↓ + Na⁺ + NO₃⁻',
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net_ion: 'Ag⁺ + Cl⁻ → AgCl↓',
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type: 'precip', pcolor: '#F5F5F5', pname: 'AgCl — белый творожистый осадок',
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sign: '↓', signColor: '#F5F5F5',
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},
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co3_hcl: {
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name: 'Na₂CO₃ + HCl',
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left: [{ f: 'Na⁺', color: '#FFD54F', count: 10 }, { f: 'CO₃²⁻', color: '#CE93D8', count: 5 }],
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right: [{ f: 'H⁺', color: '#EF5350', count: 10 }, { f: 'Cl⁻', color: '#AED581', count: 10 }],
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reacts: ['CO₃²⁻', 'H⁺'],
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spectators: ['Na⁺', 'Cl⁻'],
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product: { f: 'CO₂↑', color: '#B0BEC5' },
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mol: 'Na₂CO₃ + 2HCl → 2NaCl + CO₂↑ + H₂O',
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full_ion: '2Na⁺ + CO₃²⁻ + 2H⁺ + 2Cl⁻ → 2Na⁺ + 2Cl⁻ + CO₂↑ + H₂O',
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net_ion: 'CO₃²⁻ + 2H⁺ → CO₂↑ + H₂O',
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type: 'gas', gcolor: '#B0BEC5', gname: 'CO₂ — углекислый газ',
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sign: '↑', signColor: '#B0BEC5',
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},
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pb_i: {
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name: 'Pb(NO₃)₂ + KI',
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left: [{ f: 'Pb²⁺', color: '#F48FB1', count: 6 }, { f: 'NO₃⁻', color: '#FFCC02', count: 12 }],
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right: [{ f: 'K⁺', color: '#80CBC4', count: 12 }, { f: 'I⁻', color: '#CE93D8', count: 12 }],
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reacts: ['Pb²⁺', 'I⁻'],
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spectators: ['NO₃⁻', 'K⁺'],
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product: { f: 'PbI₂', color: '#F9A825' },
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mol: 'Pb(NO₃)₂ + 2KI → PbI₂↓ + 2KNO₃',
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full_ion: 'Pb²⁺ + 2NO₃⁻ + 2K⁺ + 2I⁻ → PbI₂↓ + 2K⁺ + 2NO₃⁻',
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net_ion: 'Pb²⁺ + 2I⁻ → PbI₂↓',
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type: 'precip', pcolor: '#F9A825', pname: 'PbI₂ — ярко-жёлтый осадок',
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sign: '↓', signColor: '#F9A825',
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},
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ca_co3: {
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name: 'CaCl₂ + Na₂CO₃',
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left: [{ f: 'Ca²⁺', color: '#FF8A65', count: 8 }, { f: 'Cl⁻', color: '#AED581', count: 16 }],
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right: [{ f: 'Na⁺', color: '#FFD54F', count: 16 }, { f: 'CO₃²⁻', color: '#CE93D8', count: 8 }],
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reacts: ['Ca²⁺', 'CO₃²⁻'],
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spectators: ['Cl⁻', 'Na⁺'],
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product: { f: 'CaCO₃', color: '#F5F5F5' },
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mol: 'CaCl₂ + Na₂CO₃ → CaCO₃↓ + 2NaCl',
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full_ion: 'Ca²⁺ + 2Cl⁻ + 2Na⁺ + CO₃²⁻ → CaCO₃↓ + 2Na⁺ + 2Cl⁻',
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net_ion: 'Ca²⁺ + CO₃²⁻ → CaCO₃↓',
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type: 'precip', pcolor: '#F5F5F5', pname: 'CaCO₃ — белый осадок (мел)',
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sign: '↓', signColor: '#F5F5F5',
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},
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};
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constructor(canvas) {
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this.canvas = canvas;
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this.ctx = canvas.getContext('2d');
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this.rxnId = 'ba_so4';
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this._raf = null;
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this._last = 0;
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this._t = 0;
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this._phase = 'idle'; // idle | mixing | pairing | done
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this._prog = 0;
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this._stepIdx = 0;
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this._stepTimer = 0;
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this._ions = [];
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this._pairs = [];
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this._precip = [];
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this._gas = [];
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/* edu-tooltip */
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this._eduTooltipAge = -1;
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this._eduTooltipLines = [];
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/* product label */
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this._prodLabelAge = -1;
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this._prodLabelText = '';
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this._prodLabelType = 'precip';
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this.W = 0; this.H = 0;
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this.onUpdate = null;
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this.fit();
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this._initIons();
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}
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fit() {
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const dpr = window.devicePixelRatio || 1;
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const W = this.canvas.offsetWidth || 600;
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const H = this.canvas.offsetHeight || 400;
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this.canvas.width = Math.round(W * dpr);
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this.canvas.height = Math.round(H * dpr);
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this.ctx.setTransform(dpr, 0, 0, dpr, 0, 0);
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this.W = W; this.H = H;
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this._initIons();
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}
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setReaction(id) {
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if (!IonExSim.RXN[id]) return;
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this.rxnId = id;
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this.reset();
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}
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reset() {
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this._phase = 'idle'; this._prog = 0;
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this._stepIdx = 0; this._stepTimer = 0;
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this._pairs = []; this._precip = []; this._gas = [];
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this._initIons();
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this.draw();
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}
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_initIons() {
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const { W, H } = this;
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const rxn = IonExSim.RXN[this.rxnId];
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const bTop = H * 0.10, bBot = H * 0.78;
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this._ions = [];
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/* Left beaker ions */
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rxn.left.forEach(spec => {
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for (let i = 0; i < spec.count; i++) {
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this._ions.push({
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x: W * 0.10 + Math.random() * W * 0.36,
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y: bTop + 20 + Math.random() * (bBot - bTop - 40),
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vx: (Math.random() - 0.5) * 0.8, vy: (Math.random() - 0.5) * 0.8,
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spec: spec.f, color: spec.color,
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r: 8 + Math.random() * 3,
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phase: Math.random() * Math.PI * 2,
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active: true, side: 'L',
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reacts: rxn.reacts.includes(spec.f),
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paired: false,
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});
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}
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});
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/* Right beaker ions */
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rxn.right.forEach(spec => {
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for (let i = 0; i < spec.count; i++) {
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this._ions.push({
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x: W * 0.54 + Math.random() * W * 0.36,
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y: bTop + 20 + Math.random() * (bBot - bTop - 40),
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vx: (Math.random() - 0.5) * 0.8, vy: (Math.random() - 0.5) * 0.8,
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spec: spec.f, color: spec.color,
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r: 8 + Math.random() * 3,
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phase: Math.random() * Math.PI * 2,
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active: true, side: 'R',
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reacts: rxn.reacts.includes(spec.f),
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paired: false,
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});
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}
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});
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}
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start() {
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if (this._phase !== 'idle') this.reset();
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this._phase = 'mixing'; this._prog = 0;
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if (window.LabFX) {
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LabFX.sound.play('pour');
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const { W, H } = this;
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LabFX.particles.emit({ ctx: this.ctx, x: W * 0.3, y: H * 0.4, count: 10,
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color: '#4CC9F0', speed: 40, spread: 2.0, angle: 0,
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gravity: 120, life: 700, shape: 'splash' });
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LabFX.particles.emit({ ctx: this.ctx, x: W * 0.7, y: H * 0.4, count: 10,
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color: '#EF476F', speed: 40, spread: 2.0, angle: 0,
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gravity: 120, life: 700, shape: 'splash' });
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}
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if (this._raf) return;
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this._last = performance.now();
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const loop = t => { this._raf = requestAnimationFrame(loop); this._tick(t); };
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this._raf = requestAnimationFrame(loop);
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}
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stop() { cancelAnimationFrame(this._raf); this._raf = null; }
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/* ── Физика ─────────────────────────────────────────────────────── */
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_tick(t) {
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const dt = Math.min((t - this._last) / 1000, 0.05);
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this._last = t; this._t += dt;
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if (window.LabFX) LabFX.particles.update(dt);
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const { W, H } = this;
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const rxn = IonExSim.RXN[this.rxnId];
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if (this._phase === 'mixing') {
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this._prog = Math.min(1, this._prog + dt * 0.32);
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this._ions.forEach(ion => {
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if (!ion.active) return;
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const tx = W * 0.5 + (Math.random() - 0.5) * W * 0.72;
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const ty = H * 0.44 + (Math.random() - 0.5) * H * 0.38;
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ion.vx += (tx - ion.x) * 0.003 * this._prog;
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ion.vy += (ty - ion.y) * 0.003 * this._prog;
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ion.vx += (Math.random() - 0.5) * 0.7;
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ion.vy += (Math.random() - 0.5) * 0.7;
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ion.vx *= 0.88; ion.vy *= 0.88;
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ion.x += ion.vx; ion.y += ion.vy;
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ion.phase += dt * 2;
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this._clampIon(ion);
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});
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if (this._prog >= 1) { this._phase = 'pairing'; this._prog = 0; }
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}
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if (this._phase === 'pairing') {
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this._prog = Math.min(1, this._prog + dt * 0.16);
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this._stepTimer += dt;
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if (this._stepTimer > 1.5 && this._stepIdx < 2) { this._stepIdx++; this._stepTimer = 0; }
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this._ions.forEach(ion => {
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if (!ion.active || ion.paired) return;
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ion.vx += (Math.random() - 0.5) * 0.8;
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ion.vy += (Math.random() - 0.5) * 0.8;
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ion.vx *= 0.88; ion.vy *= 0.88;
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ion.x += ion.vx; ion.y += ion.vy;
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ion.phase += dt * 2;
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this._clampIon(ion);
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});
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/* Pair up reactive ions */
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if (Math.random() < 0.10 * (0.5 + this._prog)) this._doPair(rxn);
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/* Animate pairs */
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this._pairs.forEach(p => {
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p.flashT = Math.max(0, p.flashT - dt * 2.5);
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if (rxn.type === 'precip') {
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p.vy = Math.min(p.vy + 0.15, 5);
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p.y += p.vy;
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if (p.y >= H * 0.78 && !p.settled) {
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p.y = H * 0.78; p.vy = 0; p.settled = true;
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this._precip.push({ x: p.x, y: p.y, r: p.r, id: p.id });
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if (window.LabFX) {
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const now2 = performance.now();
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if (!this._fxFizzLast || now2 - this._fxFizzLast > 800) {
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this._fxFizzLast = now2;
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LabFX.sound.play('fizz');
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}
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LabFX.particles.emit({ ctx: this.ctx, x: p.x, y: H * 0.78, count: 5,
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color: '#888888', speed: 15, spread: 1.8, angle: -Math.PI / 2,
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gravity: 30, life: 1200, shape: 'dust' });
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}
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}
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} else if (rxn.type === 'gas') {
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p.vy = Math.max(p.vy - 0.08, -4);
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p.y += p.vy;
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p.alpha = Math.max(0, p.alpha - 0.004);
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}
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});
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this._pairs = this._pairs.filter(p => !p.settled && (p.alpha === undefined || p.alpha > 0));
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if (this._prog >= 1) { this._phase = 'done'; this._stepIdx = 2; }
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}
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if (this._phase === 'done') {
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this._ions.forEach(ion => {
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if (!ion.active || ion.paired) return;
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ion.vx += (Math.random() - 0.5) * 0.45;
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ion.vy += (Math.random() - 0.5) * 0.45;
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ion.vx *= 0.92; ion.vy *= 0.92;
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ion.x += ion.vx; ion.y += ion.vy;
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ion.phase += dt;
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this._clampIon(ion);
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});
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/* trigger product label + edu-tooltip once on transition to done */
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if (window.ChemVisuals && this._prodLabelAge < 0) {
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const rxn = IonExSim.RXN[this.rxnId];
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if (rxn.type === 'precip') {
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this._prodLabelText = (rxn.pname || '') + ' ';
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this._prodLabelType = 'precip';
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this._prodLabelAge = 0;
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} else if (rxn.type === 'gas') {
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this._prodLabelText = (rxn.gname || '') + ' ';
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this._prodLabelType = 'gas';
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this._prodLabelAge = 0;
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}
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/* edu tooltip from reaction net_ion */
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if (this._eduTooltipAge < 0) {
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const netIon = (rxn.net_ion || '').replace(/→/g, '->');
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this._eduTooltipLines = [
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'Краткое ионное уравнение:',
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netIon.length > 32 ? netIon.slice(0, 32) + '...' : netIon,
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(rxn.pname || rxn.gname || '').slice(0, 34),
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].filter(Boolean).slice(0, 4);
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this._eduTooltipAge = 0;
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}
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}
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}
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/* advance ages */
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if (this._eduTooltipAge >= 0) {
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this._eduTooltipAge += dt / 4.0;
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if (this._eduTooltipAge >= 1.0) this._eduTooltipAge = -1;
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}
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if (this._prodLabelAge >= 0) {
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this._prodLabelAge += dt / 3.0;
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if (this._prodLabelAge >= 1.0) this._prodLabelAge = -1;
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}
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this.draw();
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if (this.onUpdate) this.onUpdate(this.info());
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}
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_clampIon(ion) {
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const { W, H } = this;
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const bTop = H * 0.10, bBot = H * 0.78;
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if (ion.x < ion.r + 6) { ion.x = ion.r + 6; ion.vx *= -0.5; }
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if (ion.x > W - ion.r - 6) { ion.x = W - ion.r - 6; ion.vx *= -0.5; }
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if (ion.y < bTop + ion.r) { ion.y = bTop + ion.r; ion.vy *= -0.5; }
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if (ion.y > bBot - ion.r) { ion.y = bBot - ion.r; ion.vy *= -0.5; }
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}
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_doPair(rxn) {
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const r1 = rxn.reacts[0], r2 = rxn.reacts[1];
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const pool1 = this._ions.filter(i => i.active && !i.paired && i.spec === r1);
|
|
const pool2 = this._ions.filter(i => i.active && !i.paired && i.spec === r2);
|
|
if (!pool1.length || !pool2.length) return;
|
|
const a = pool1[Math.floor(Math.random() * pool1.length)];
|
|
const b = pool2[Math.floor(Math.random() * pool2.length)];
|
|
a.paired = true; b.paired = true;
|
|
a.active = false; b.active = false;
|
|
this._pairs.push({
|
|
id: this._t + Math.random(),
|
|
x: (a.x + b.x) / 2, y: (a.y + b.y) / 2,
|
|
vy: rxn.type === 'gas' ? -2 : 0,
|
|
r: 7, flashT: 1, settled: false, alpha: 1,
|
|
});
|
|
}
|
|
|
|
/* ── Рендеринг ──────────────────────────────────────────────────── */
|
|
|
|
draw() {
|
|
const { ctx, W, H } = this;
|
|
const rxn = IonExSim.RXN[this.rxnId];
|
|
|
|
ctx.fillStyle = '#07071A';
|
|
ctx.fillRect(0, 0, W, H);
|
|
|
|
/* Dot grid */
|
|
ctx.fillStyle = 'rgba(255,255,255,0.07)';
|
|
for (let x = 0; x < W; x += 28) {
|
|
for (let y = 0; y < H; y += 28) {
|
|
ctx.beginPath(); ctx.arc(x, y, 0.8, 0, Math.PI * 2); ctx.fill();
|
|
}
|
|
}
|
|
|
|
/* desk */
|
|
if (window.ChemVisuals) {
|
|
ChemVisuals.drawDeskBackground(ctx, W, H, H * 0.80);
|
|
}
|
|
|
|
if (this._phase === 'idle') {
|
|
this._drawTwoBeakers(ctx, W, H, rxn);
|
|
} else {
|
|
this._drawSingleBeaker(ctx, W, H);
|
|
}
|
|
|
|
this._drawIons(ctx, rxn);
|
|
this._drawPairs(ctx, rxn);
|
|
this._drawPrecipitate(ctx, rxn);
|
|
this._drawPanel(ctx, W, H, rxn);
|
|
if (window.LabFX) LabFX.particles.draw(ctx);
|
|
|
|
/* animated product label */
|
|
if (window.ChemVisuals && this._prodLabelAge >= 0) {
|
|
const labelY = this._prodLabelType === 'gas' ? H * 0.12 : H * 0.74;
|
|
ChemVisuals.drawProductLabel(ctx, W / 2, labelY, this._prodLabelText, this._prodLabelType, this._prodLabelAge);
|
|
if (this._prodLabelType === 'gas') {
|
|
ChemVisuals.animateGasBubbles(ctx, W / 2, H * 0.15, 'rgba(200,235,255,0.8)', this._t);
|
|
} else {
|
|
ChemVisuals.animatePrecipitateFall(ctx, W / 2, H * 0.72, rxn.pcolor || '#CCC', this._t);
|
|
}
|
|
}
|
|
|
|
/* edu tooltip */
|
|
if (window.ChemVisuals && this._eduTooltipAge >= 0 && this._eduTooltipLines.length > 0) {
|
|
ChemVisuals.drawEduTooltip(ctx, W / 2, H * 0.10, 210, this._eduTooltipLines, this._eduTooltipAge);
|
|
}
|
|
}
|
|
|
|
_drawTwoBeakers(ctx, W, H, rxn) {
|
|
const drawB = (x, y, w, h, ions) => {
|
|
ctx.save();
|
|
ctx.strokeStyle = 'rgba(120,185,255,0.55)'; ctx.lineWidth = 2;
|
|
ctx.beginPath();
|
|
ctx.moveTo(x, y); ctx.lineTo(x, y + h);
|
|
ctx.lineTo(x + w, y + h); ctx.lineTo(x + w, y);
|
|
ctx.stroke();
|
|
ctx.beginPath(); ctx.moveTo(x - 4, y); ctx.lineTo(x + w + 4, y); ctx.stroke();
|
|
/* Rim highlight */
|
|
const hlg = ctx.createLinearGradient(x, y, x + 14, y + h);
|
|
hlg.addColorStop(0, 'rgba(200,230,255,0.15)');
|
|
hlg.addColorStop(1, 'rgba(200,230,255,0.02)');
|
|
ctx.strokeStyle = hlg; ctx.lineWidth = 5;
|
|
ctx.beginPath(); ctx.moveTo(x + 7, y + 6); ctx.lineTo(x + 7, y + h - 6); ctx.stroke();
|
|
/* Formula label */
|
|
ctx.fillStyle = 'rgba(255,255,255,0.22)'; ctx.font = 'bold 11px monospace';
|
|
ctx.textAlign = 'center'; ctx.textBaseline = 'bottom';
|
|
const label = ions.map(s => s.f).join(', ');
|
|
ctx.fillText(label, x + w / 2, y - 4);
|
|
ctx.restore();
|
|
};
|
|
const bTop = H * 0.10, bH = H * 0.70;
|
|
drawB(W * 0.04, bTop, W * 0.40, bH, rxn.left);
|
|
drawB(W * 0.56, bTop, W * 0.40, bH, rxn.right);
|
|
|
|
/* Mix arrow */
|
|
ctx.save();
|
|
const mx = W * 0.50, my = H * 0.44;
|
|
ctx.strokeStyle = 'rgba(255,255,255,0.22)'; ctx.lineWidth = 2;
|
|
ctx.fillStyle = 'rgba(255,255,255,0.22)';
|
|
ctx.beginPath(); ctx.moveTo(mx - 16, my); ctx.lineTo(mx + 16, my); ctx.stroke();
|
|
ctx.beginPath(); ctx.moveTo(mx + 10, my - 5); ctx.lineTo(mx + 16, my); ctx.lineTo(mx + 10, my + 5); ctx.fill();
|
|
ctx.restore();
|
|
}
|
|
|
|
_drawSingleBeaker(ctx, W, H) {
|
|
const bx = W * 0.04, by = H * 0.08, bw = W * 0.92, bh = H * 0.72;
|
|
ctx.save();
|
|
ctx.strokeStyle = 'rgba(120,185,255,0.60)'; ctx.lineWidth = 2.5;
|
|
ctx.beginPath();
|
|
ctx.moveTo(bx, by); ctx.lineTo(bx, by + bh);
|
|
ctx.lineTo(bx + bw, by + bh); ctx.lineTo(bx + bw, by);
|
|
ctx.stroke();
|
|
ctx.beginPath(); ctx.moveTo(bx - 5, by); ctx.lineTo(bx + bw + 5, by); ctx.stroke();
|
|
const hlg = ctx.createLinearGradient(bx, by, bx + 18, by + bh);
|
|
hlg.addColorStop(0, 'rgba(200,230,255,0.18)');
|
|
hlg.addColorStop(1, 'rgba(200,230,255,0.02)');
|
|
ctx.strokeStyle = hlg; ctx.lineWidth = 6;
|
|
ctx.beginPath(); ctx.moveTo(bx + 8, by + 8); ctx.lineTo(bx + 8, by + bh - 8); ctx.stroke();
|
|
ctx.restore();
|
|
}
|
|
|
|
_drawIons(ctx, rxn) {
|
|
this._ions.forEach(ion => {
|
|
if (!ion.active) return;
|
|
const isSpec = rxn.spectators.includes(ion.spec);
|
|
ctx.save();
|
|
ctx.globalAlpha = (isSpec && this._phase !== 'idle') ? 0.40 : 0.88;
|
|
ctx.shadowColor = ion.color;
|
|
ctx.shadowBlur = 7 + Math.sin(ion.phase) * 3;
|
|
ctx.beginPath(); ctx.arc(ion.x, ion.y, ion.r, 0, Math.PI * 2);
|
|
ctx.fillStyle = ion.color; ctx.fill();
|
|
ctx.strokeStyle = 'rgba(255,255,255,0.18)'; ctx.lineWidth = 1; ctx.stroke();
|
|
ctx.shadowBlur = 0; ctx.globalAlpha = 1;
|
|
/* Formula label */
|
|
const fs = Math.min(Math.round(ion.r * 0.60), 9);
|
|
ctx.fillStyle = 'rgba(0,0,0,0.80)';
|
|
ctx.font = `bold ${fs}px monospace`;
|
|
ctx.textAlign = 'center'; ctx.textBaseline = 'middle';
|
|
ctx.fillText(ion.spec, ion.x, ion.y);
|
|
ctx.restore();
|
|
});
|
|
}
|
|
|
|
_drawPairs(ctx, rxn) {
|
|
const pcolor = rxn.pcolor || rxn.gcolor || '#FFF';
|
|
this._pairs.forEach(p => {
|
|
ctx.save();
|
|
const alpha = p.alpha !== undefined ? p.alpha : 1;
|
|
ctx.globalAlpha = alpha * 0.92;
|
|
ctx.shadowColor = p.flashT > 0 ? '#FFFFFF' : pcolor;
|
|
ctx.shadowBlur = p.flashT > 0 ? 28 * p.flashT : 8;
|
|
ctx.beginPath(); ctx.arc(p.x, p.y, p.r, 0, Math.PI * 2);
|
|
ctx.fillStyle = p.flashT > 0 ? `rgba(255,255,255,${p.flashT * 0.9})` : pcolor;
|
|
ctx.fill();
|
|
ctx.shadowBlur = 0; ctx.globalAlpha = 1;
|
|
/* Product label */
|
|
ctx.fillStyle = 'rgba(0,0,0,0.80)';
|
|
ctx.font = 'bold 7px monospace';
|
|
ctx.textAlign = 'center'; ctx.textBaseline = 'middle';
|
|
ctx.fillText(rxn.product.f, p.x, p.y);
|
|
ctx.restore();
|
|
});
|
|
}
|
|
|
|
_drawPrecipitate(ctx, rxn) {
|
|
if (rxn.type !== 'precip' || !this._precip.length) return;
|
|
ctx.save();
|
|
this._precip.forEach(p => {
|
|
ctx.shadowColor = rxn.pcolor; ctx.shadowBlur = 3;
|
|
ctx.beginPath(); ctx.arc(p.x, p.y, p.r, 0, Math.PI * 2);
|
|
ctx.fillStyle = rxn.pcolor; ctx.fill();
|
|
});
|
|
ctx.restore();
|
|
if (this._precip.length > 4) {
|
|
ctx.save();
|
|
ctx.fillStyle = rxn.pcolor; ctx.font = 'bold 10px monospace';
|
|
ctx.textAlign = 'center'; ctx.textBaseline = 'bottom';
|
|
ctx.shadowColor = rxn.pcolor; ctx.shadowBlur = 6;
|
|
ctx.fillText(`↓ ${rxn.pname}`, this.W / 2, this.H * 0.80 - 4);
|
|
ctx.restore();
|
|
}
|
|
}
|
|
|
|
_drawPanel(ctx, W, H, rxn) {
|
|
const py = H * 0.82;
|
|
ctx.fillStyle = 'rgba(7,7,26,0.95)';
|
|
ctx.fillRect(0, py, W, H - py);
|
|
ctx.strokeStyle = 'rgba(100,165,255,0.22)'; ctx.lineWidth = 1;
|
|
ctx.beginPath(); ctx.moveTo(0, py); ctx.lineTo(W, py); ctx.stroke();
|
|
|
|
if (this._phase === 'idle') {
|
|
ctx.fillStyle = '#37474F'; ctx.font = '11px monospace';
|
|
ctx.textAlign = 'center'; ctx.textBaseline = 'middle';
|
|
ctx.fillText('← Нажми «Смешать» для начала реакции →', W / 2, py + (H - py) / 2);
|
|
return;
|
|
}
|
|
|
|
const steps = [
|
|
{ lbl: 'Молекулярное:', txt: rxn.mol, col: '#B0BEC5' },
|
|
{ lbl: 'Полное ионное:', txt: rxn.full_ion, col: '#CE93D8' },
|
|
{ lbl: 'Краткое ионное:', txt: rxn.net_ion, col: '#FFD166' },
|
|
];
|
|
|
|
const panH = H - py;
|
|
const n = Math.min(this._stepIdx + 1, steps.length);
|
|
for (let i = 0; i < n; i++) {
|
|
const s = steps[i];
|
|
const y = py + 11 + i * (panH * 0.29);
|
|
ctx.save();
|
|
if (i === this._stepIdx && this._phase !== 'done') {
|
|
ctx.fillStyle = 'rgba(255,255,255,0.04)';
|
|
ctx.fillRect(8, y - 9, W - 16, 20);
|
|
}
|
|
ctx.fillStyle = s.col; ctx.font = 'bold 9.5px monospace';
|
|
ctx.textAlign = 'left'; ctx.textBaseline = 'middle';
|
|
ctx.fillText(s.lbl, 14, y);
|
|
ctx.fillStyle = (i === this._stepIdx && this._phase !== 'done') ? '#FFF' : 'rgba(255,255,255,0.62)';
|
|
ctx.font = '9.5px monospace';
|
|
ctx.fillText(s.txt, 14 + ctx.measureText(s.lbl).width + 8, y);
|
|
ctx.restore();
|
|
}
|
|
|
|
if (this._phase === 'done') {
|
|
ctx.save();
|
|
ctx.fillStyle = rxn.signColor; ctx.font = 'bold 10px monospace';
|
|
ctx.textAlign = 'right'; ctx.textBaseline = 'top';
|
|
ctx.shadowColor = rxn.signColor; ctx.shadowBlur = 8;
|
|
const label = rxn.type === 'precip' ? `✓ ${rxn.sign} осадок` : `✓ ${rxn.sign} газ`;
|
|
ctx.fillText(label, W - 14, py + 3);
|
|
ctx.restore();
|
|
}
|
|
}
|
|
|
|
info() {
|
|
const rxn = IonExSim.RXN[this.rxnId];
|
|
return {
|
|
rxn: rxn.name,
|
|
phase: this._phase,
|
|
prog: Math.round(this._prog * 100),
|
|
precip: this._precip.length,
|
|
};
|
|
}
|
|
}
|